| 1 | Muriel Hurtis | FRA | 22,49 | Q | NR |
| 2 | Natalya Safronnikova | BLR | 22,91 | Q | NR |
| 3 | Marina Maydanova | UKR | 23,26 | ||
| 4 | Yuliya Tabakova | RUS | 23,64 |
| 1 | Michelle Collins | USA | 22,31 | Q | NR |
| 2 | Juliet Campbell | JAM | 22,84 | Q | |
| 3 | Ciara Sheehy | IRL | 23,23 | ||
| 4 | Manuela Levorato | ITA | 23,52 |
| 1 | Anastasiya Kapachinskaya | RUS | 22,76 | Q |
| 2 | Cydonie Mothersill | CAY | 22,85 | Q |
| 3 | Allyson Felix | USA | 23,29 | |
| 4 | Amy Spencer | GBR | 23,73 |