| 1 | Ivet Lalova | BUL | 23,08 | Q |
| 2 | Yekaterina Kondratyeva | RUS | 23,27 | Q |
| 3 | Anna Pacholak | POL | 23,45 | Q |
| 4 | Lina Jacques-Sébastien | FRA | 23,49 | |
| 5 | Sylviane Félix | FRA | 23,93 |
| 1 | Karin Mayr-Krifka | AUT | 23,24 | Q |
| 2 | Jacqueline Poelman | NED | 23,54 | Q |
| 3 | Fabé Dia | FRA | 23,57 | Q |
| 4 | Angela Morosanu | ROM | 23,63 | |
| 5 | Alenka Bikar | SLO | 23,82 |